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Yes. PayPal members may have one Personal account and one Premier or Business account. You can add additional email addresses, credit cards and debit cards, and bank accounts to your Personal, Premier or Business account. However, each account must have its own email address and financial information. If only one account is needed you may also upgrade from a Personal account to a premier or business account
merchant services
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As I know, I just know PayPaly and Credit card these two payment.But I don't know if it's possible to have two accounts or not. Now, I learnt from here, Thanks very much!